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With specific values for C a and K a this quadratic equation can be solved for x. Assuming [4] that pH = −log 10 [H +] the pH can be calculated as pH = −log 10 x. If the degree of dissociation is quite small, C a ≫ x and the expression simplifies to = and pH = 1 / 2 (pK a − log C a).
The degree of dissociation in gases is denoted by the symbol α, where α refers to the percentage of gas molecules which dissociate. Various relationships between K p and α exist depending on the stoichiometry of the equation. The example of dinitrogen tetroxide (N 2 O 4) dissociating to nitrogen dioxide (NO 2) will be taken.
The dissociation rate constant is defined using K off. [2] The Michaelis-Menten constant is denoted by K m and is represented by the equation K m = (K off + K cat)/ K on [definition needed]. The rates that the enzyme binds and dissociates from the substrate are represented by K on and K off respectively.
Melting curve analysis is an assessment of the dissociation characteristics of double-stranded DNA during heating. As the temperature is raised, the double strand begins to dissociate leading to a rise in the absorbance intensity, hyperchromicity. The temperature at which 50% of DNA is denatured is known as the melting temperature. Measurement ...
The bond-dissociation energy of a bond is the amount of energy required to cleave the bond homolytically. This enthalpy change is one measure of bond strength . The triplet excitation energy of a sigma bond is the energy required for homolytic dissociation, but the actual excitation energy may be higher than the bond-dissociation energy due to ...
Other structural factors that influence the magnitude of the acid dissociation constant include inductive effects, mesomeric effects, and hydrogen bonding. Hammett type equations have frequently been applied to the estimation of pK a. [3] [4] The quantitative behaviour of acids and bases in solution can be understood only if their pK a values ...
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
Lab notebook with the complete record of the experiments underlying a published paper. [1] Chemistry stencils that used to be used for drawing equipment in lab notebooks. A laboratory notebook (colloq. lab notebook or lab book) is a primary record of research.