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In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Ammonia is moderately basic; a 1.0 M aqueous solution has a pH of 11.6, and if a strong acid is added to such a solution until the solution is neutral (pH = 7), 99.4% of the ammonia molecules are protonated. Temperature and salinity also affect the proportion of ammonium [NH 4] +.
The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 2 ] [ 3 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
A typical task in chemistry is the preparation of 100 mL (= 0.1 L) of a 2 mol/L solution of NaCl in water. The mass of salt needed is m (NaCl) = 2 mol/L × 0.1 L × 58 g/mol = 11.6 g.
The first step (called SC-1, where SC stands for Standard Clean) is performed with a solution of (ratios may vary) [2] 5 parts of deionized water; 1 part of ammonia water, (29% by weight of NH 3) 1 part of aqueous H 2 O 2 (hydrogen peroxide, 30%) at 75 or 80 °C [1] typically for 10 minutes. This base-peroxide mixture removes organic residues.
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The Solvay process or ammonia–soda process is the major industrial process for the production of sodium carbonate (soda ash, Na 2 CO 3).The ammonia–soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. [1]
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