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2 O consists of [Fe(H 2 O) 6] 2+ centers and one "lattice water". Water is typically a monodentate ligand, i.e., it forms only one bond with the central atom. [89] Some hydrogen-bonding contacts in FeSO 4. 7H 2 O. This metal aquo complex crystallizes with one molecule of "lattice" water, which interacts with the sulfate and with the [Fe(H 2 O ...
Of the 32 point groups that exist in three dimensions, most are assigned to only one lattice system, in which case the crystal system and lattice system both have the same name. However, five point groups are assigned to two lattice systems, rhombohedral and hexagonal, because both lattice systems exhibit threefold rotational symmetry.
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The structure of liquids, glasses and other non-crystalline solids is characterized by the absence of long-range order which defines crystalline materials. Liquids and amorphous solids do, however, possess a rich and varied array of short to medium range order, which originates from chemical bonding and related interactions.
For instance, water warms when treated with CaCl 2 (anhydrous calcium chloride) as a consequence of the large heat of hydration. However, the hexahydrate, CaCl 2 ·6H 2 O cools the water upon dissolution. The latter happens because the hydration energy does not completely overcome the lattice energy, and the remainder has to be taken from the ...
The second water in the formula unit is hydrogen-bonded to the chloride and to the coordinated water molecule. Water of crystallization is stabilized by electrostatic attractions, consequently hydrates are common for salts that contain +2 and +3 cations as well as −2 anions. In some cases, the majority of the weight of a compound arises from ...
Chemical structure of cholesteryl benzoate molecule. He found that cholesteryl benzoate does not melt in the same manner as other compounds, but has two melting points. At 145.5 °C (293.9 °F) it melts into a cloudy liquid, and at 178.5 °C (353.3 °F) it melts again and the cloudy liquid becomes clear. The phenomenon is reversible.
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...