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Directed self-assembly (DSA) is a type of directed assembly which utilizes block co-polymer morphology to create lines, space and hole patterns, facilitating for a more accurate control of the feature shapes. Then it uses surface interactions as well as polymer thermodynamics to finalize the formation of the final pattern shapes. [1]
Jimmy W. Mays is an American polymer scientist, academic, and author.He is a Professor Emeritus at the University of Tennessee. [1]Mays is most known for his works on polymer chemistry, block copolymers, and composite materials.
Self-assembly is a process which is easily influenced by external parameters. This feature can make synthesis rather complex because of the need to control many free parameters. Yet self-assembly has the advantage that a large variety of shapes and functions on many length scales can be obtained. [31]
His past research concerned the self-assembly of block copolymers. Most recently he has developed interests in peptide and peptide conjugate self-assembly, including molecules with bioactivity such as amyloid peptides peptide hormones, antimicrobial peptides, peptides in cosmetic applications and peptides with anti-cancer activity. Several of ...
[3] [1] He was granted fellowship in the American Physical Society in 2008 "[f]or fundamental and insightful research on the dimension dependent properties of polymer nanostructures, the directed self-assembly of block copolymers, and their application in the development of advanced lithographic materials and processes."
These kinetic effects, such as trapping in metastable states, slow coarsening kinetics, and pathway-dependent assembly, are often viewed as complications to be overcome in, for example, the formation of block copolymers. [12] [18] Amphiphile self-assembly is an essential bottom-up approach of fabricating advanced functional materials.
block copolymer: A copolymer that is a block polymer. In the constituent macromolecules of a block copolymer , adjacent blocks are constitutionally different, i.e. adjacent blocks comprise constitutional unit derived from different species of monomer or from the same species of monomer but with a different composition or sequence distribution ...
Living polymerization is a popular method for synthesizing block copolymers since the polymer can be synthesized in stages, each stage containing a different monomer. Additional advantages are predetermined molar mass and control over end-groups .