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Crystal structure of CH 3 NH 3 PbX 3 perovskites (X=I, Br and/or Cl). The methylammonium cation (CH 3 NH 3 +) is surrounded by PbX 6 octahedra. [13]The name "perovskite solar cell" is derived from the ABX 3 crystal structure of the absorber materials, referred to as perovskite structure, where A and B are cations and X is an anion.
Double perovskite nanocrystals such as Cs 2 AgBiX 6 (X = Cl, Br, I), [164] Cs 2 AgInCl 6 (including Mn-doped variant), [165] and Cs 2 AgIn x Bi 1−x Cl 6 [166] (including Na-doped variant) [167] have been studied as potential alternatives to lead-halide perovskites, although none exhibit narrow, high PLQY emission.
Methylammonium lead halides (MALHs) are solid compounds with perovskite structure and a chemical formula of [CH 3 NH 3] + Pb 2+ (X −) 3, where X = Cl, Br or I. They have potential applications in solar cells , [ 2 ] lasers , light-emitting diodes , photodetectors , radiation detectors, [ 3 ] [ 4 ] scintillator , [ 5 ] magneto-optical data ...
Perovskite (pronunciation: / p ə ˈ r ɒ v s k aɪ t /) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula Ca Ti O 3).Its name is also applied to the class of compounds which have the same type of crystal structure as CaTiO 3, known as the perovskite structure, which has a general chemical formula A 2+ B 4+ (X 2−) 3. [6]
Ruddlesden-Popper (RP) phases are a type of perovskite structure that consists of two-dimensional perovskite-like slabs interleaved with cations.The general formula of an RP phase is A n+1 B n X 3n+1, where A and B are cations, X is an anion (e.g., oxygen), and n is the number of octahedral layers in the perovskite-like stack. [1]
Tin-based perovskites have shown excellent mobility in transistors [1] which gives them an opportunity to be explored more for solar cell applications. Tin halide perovskites, despite being regarded as semiconductors, often display metallic-like behavior due to the inadvertent and/or spontaneous hole carrier doping resulting from the easy ...
Ordered double perovskites are usually denoted as A 2 BB ′ O 6 where disordered are denoted as A(BB ′)O 3. In ordered perovskites, three different types of ordering are possible: rock-salt, layered, and columnar. The most common ordering is rock-salt followed by the much more uncommon disordered and very distant columnar and layered. [15]
Tin-based perovskites have the potential to outperform the PCE and stability of lead-based perovskite solar cells. [17] There are lots of ways to enhance the stability. Several experimental and simulation studies have predicted that the addition of the cesium Cs + can enhance the thermodynamic structural stability of FASnI3, prevent Sn2 ...