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A titration curve is a curve in graph the x-coordinate of which represents the volume of titrant added since the beginning of the titration, and the y-coordinate of which represents the concentration of the analyte at the corresponding stage of the titration (in an acid–base titration, the y-coordinate usually represents the pH of the solution).
An example of an acidimetric titration involving a strong base is as follows: Ba(OH) 2 + 2 H + → Ba 2+ + 2 H 2 O. In this case, the strong base (Ba(OH) 2) is neutralized by the acid until all of the base has reacted. This allows the viewer to calculate the concentration of the base from the volume of the standard acid that is used.
A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
The volumetric titration is based on the same principles as the coulometric titration, except that the anode solution above now is used as the titrant solution. The titrant consists of an alcohol (ROH), base (B), SO 2 and a known concentration of I 2. Pyridine has been used as the base in this case. One mole of I 2 is consumed for each mole of ...
A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the equivalence volume or end point in a strong acid-strong base titration or in a potentiometric titration.
The term also has two other, conflicting meanings. In titration, the titer is the ratio of actual to nominal concentration of a titrant, e.g. a titer of 0.5 would require 1/0.5 = 2 times more titrant than nominal. This is to compensate for possible degradation of the titrant solution.
A thermometric titration methodology which cannot be emulated using other types of titration sensors will deliver superior or results otherwise unobtainable by other techniques. Examples are the determination of fluoride by titration with boric acid, the analysis of orthophosphate by titration with magnesium ions, and the direct titration of ...
Advantages of Coulometric Titration Coulometric titration has the advantage that constant current sources for the generation of titrants are relatively easy to make. The electrochemical generation of a titrant is much more sensitive and can be much more accurately controlled than the mechanical addition of titrant using a burette drive.