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Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
Dispersion of gravity waves on a fluid surface. Phase and group velocity divided by shallow-water phase velocity √ gh as a function of relative depth h / λ. Blue lines (A): phase velocity; Red lines (B): group velocity; Black dashed line (C): phase and group velocity √ gh valid in shallow water.
In many materials the polarizability starts to saturate at high values of electric field. This saturation can be modelled by a nonlinear susceptibility . These susceptibilities are important in nonlinear optics and lead to effects such as second-harmonic generation (such as used to convert infrared light into visible light, in green laser ...
The polar water molecules surround themselves around ions in water and the energy released during the process is known as hydration enthalpy. The interaction has its immense importance in justifying the stability of various ions (like Cu 2+) in water. An ion–induced dipole force consists of an ion and a non-polar molecule interacting.
Dispersion is a process by which (in the case of solid dispersing in a liquid) agglomerated particles are separated from each other, and a new interface between the inner surface of the liquid dispersion medium and the surface of the dispersed particles is generated. This process is facilitated by molecular diffusion and convection. [4]
Spatial dispersion means that light travelling in different directions (different wavevectors) sees a slightly different permittivity tensor. Natural optical rotation requires a special material, but it also relies on the fact that the wavevector of light is nonzero, and a nonzero wavevector bypasses the symmetry restrictions on the local (zero ...
London dispersion forces are also known as 'dispersion forces', 'London forces', or 'instantaneous dipole–induced dipole forces'. The strength of London dispersion forces is proportional to the polarizability of the molecule, which in turn depends on the total number of electrons and the area over which they are spread.
Definition and higher orders [ edit ] The linear electric polarizability α {\displaystyle \alpha } in isotropic media is defined as the ratio of the induced dipole moment p {\displaystyle \mathbf {p} } of an atom to the electric field E {\displaystyle \mathbf {E} } that produces this dipole moment.