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Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
where μ is the electric dipole moment of the effectively polarized water molecule (2.35 D for the SPC/E model), μ 0 is the dipole moment of an isolated water molecule (1.85 D from experiment), and α i is an isotropic polarizability constant, with a value of 1.608 × 10 −40 F·m 2. Since the charges in the model are constant, this ...
Dispersion of gravity waves on a fluid surface. Phase and group velocity divided by shallow-water phase velocity √ gh as a function of relative depth h / λ. Blue lines (A): phase velocity; Red lines (B): group velocity; Black dashed line (C): phase and group velocity √ gh valid in shallow water.
London dispersion forces are also known as 'dispersion forces', 'London forces', or 'instantaneous dipole–induced dipole forces'. The strength of London dispersion forces is proportional to the polarizability of the molecule, which in turn depends on the total number of electrons and the area over which they are spread.
In general, force field methods are based on similar energy evaluation functionals which usually contain terms representing the bond stretching, angle bending, torsions and terms for repulsion and dispersion, such as the Buckingham potential or Lennard-Jones potential. Commonly used solvents, such as water, often have idealized models generated.
Mie theory has been used in the detection of oil concentration in polluted water. [30] [31] Mie scattering is the primary method of sizing single sonoluminescing bubbles of air in water [32] [33] [34] and is valid for cavities in materials, as well as particles in materials, as long as the surrounding material is essentially non-absorbing.
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In condensed matter physics and physical chemistry, the Lifshitz theory of van der Waals forces, sometimes called the macroscopic theory of van der Waals forces, is a method proposed by Evgeny Mikhailovich Lifshitz in 1954 for treating van der Waals forces between bodies which does not assume pairwise additivity of the individual intermolecular forces; that is to say, the theory takes into ...
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