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Manganese(VII) oxide (manganese heptoxide) is an inorganic compound with the formula Mn 2 O 7 Manganese heptoxide is a volatile liquid with an oily consistency. It is a highly reactive and powerful oxidizer that reacts explosively with nearly any organic compound .
Manganese oxide is any of a variety of manganese oxides and hydroxides. [1] These include Manganese(II) oxide, MnO; Manganese(II,III) oxide, Mn 3 O 4; Manganese(III) oxide, Mn 2 O 3; Manganese dioxide, MnO 2; Manganese(VI) oxide, MnO 3; Manganese(VII) oxide, Mn 2 O 7; Other manganese oxides include Mn 5 O 8, Mn 7 O 12 and Mn 7 O 13.
Manganese(IV) oxide was used in the original type of dry cell battery as an electron acceptor from zinc, and is the blackish material in carbon–zinc type flashlight cells. The manganese dioxide is reduced to the manganese oxide-hydroxide MnO(OH) during discharging, preventing the formation of hydrogen at the anode of the battery. [82]
Manganese(IV) oxide. Manganese forms a variety of oxides: MnO, Mn 3 O 4, Mn 2 O 3, MnO 2, MnO 3 and Mn 2 O 7. Manganese(II) oxide is an inorganic compound that forms green crystals. Like many monoxides, MnO adopts the rock salt structure, where cations and anions are both octahedrally coordinated.
Manganese dioxide also catalyses the decomposition of hydrogen peroxide to oxygen and water: 2 H 2 O 2 → 2 H 2 O + O 2. Manganese dioxide decomposes above about 530 °C to manganese(III) oxide and oxygen. At temperatures close to 1000 °C, the mixed-valence compound Mn 3 O 4 forms. Higher temperatures give MnO, which is reduced only with ...
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
Birnessite (nominally MnO 2 ·nH 2 O), also known as δ-MnO 2, is a hydrous manganese dioxide mineral with a chemical formula of Na 0.7 Ca 0.3 Mn 7 O 14 ·2.8H 2 O. [5] It is the main manganese mineral species at the Earth's surface, and commonly occurs as fine-grained, poorly crystallized aggregates in soils, sediments, grain and rock coatings (e.g., desert varnish), and marine ferromanganese ...
Generalized formula may be represented as Ba(Mn 2+)(Mn 4+) 8 O 16 (OH) 4 or as (Ba,H 2 O) 2 Mn 5 O 10. It is sometimes considered to be a hydrous manganese manganate, but of doubtful composition. The amount of manganese present corresponds to 70-80% of manganous oxide with 10-15% of available oxygen.