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Fullerene or C 60 is soccer-ball-shaped or I h with 12 pentagons and 20 hexagons. According to Euler's theorem these 12 pentagons are required for closure of the carbon network consisting of n hexagons and C 60 is the first stable fullerene because it is the smallest possible to obey this rule. In this structure none of the pentagons make ...
C 60 in solution C 60 in extra virgin olive oil showing the characteristic purple color of pristine C 60 solutions. The solubility of fullerenes is generally low. Carbon disulfide dissolves 8g/L of C60, and the best solvent (1-chloronaphthalene) dissolves 53 g/L. up Still, fullerenes are the only known allotrope of carbon that can be dissolved in common solvents at room temperature.
The closed fullerenes, especially C 60, are also informally called buckyballs for their resemblance to the standard ball of association football ("soccer"). Nested closed fullerenes have been named bucky onions. Cylindrical fullerenes are also called carbon nanotubes or buckytubes. [1] The bulk solid form of pure or mixed fullerenes is called ...
A review of works on fullerene toxicity by Lalwani et al. found little evidence that C 60 is toxic. [1] The toxicity of these carbon nanoparticles varies with dose, duration, type (e.g., C 60, C 70, M@C 60, M@C 82), functional groups used to water-solubilize these nanoparticles (e.g., OH, COOH), and method of administration (e.g., intravenous, intraperitoneal).
[2] [12] All phases of C 70 form brownish crystals with a bandgap of 1.77 eV; [2] they are n-type semiconductors where conductivity is attributed to oxygen diffusion into the solid from atmosphere. [13] The unit cell of fcc C 70 solid contains voids at 4 octahedral and 12 tetrahedral sites. [14] They are large enough to accommodate impurity atoms.
As of the early twenty-first century, the chemical and physical properties of fullerenes are still under heavy study, in both pure and applied research labs. In April 2003, fullerenes were under study for potential medicinal use — binding specific antibiotics to the structure to target resistant bacteria and even target certain cancer cells ...
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These endohedral fullerenes are usually synthesized by doping in the metal atoms in an arc reactor or by laser evaporation. These methods gives low yields of endohedral fullerenes, and a better method involves the opening of the cage, packing in the atoms or molecules, and closing the opening using certain organic reactions. This method ...