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Material dispersion can be a desirable or undesirable effect in optical applications. The dispersion of light by glass prisms is used to construct spectrometers and spectroradiometers. However, in lenses, dispersion causes chromatic aberration, an undesired effect that may degrade images in microscopes, telescopes, and photographic objectives.
A ray trace through a prism with apex angle α. Regions 0, 1, and 2 have indices of refraction, , and , and primed angles ′ indicate the ray's angle after refraction.. Ray angle deviation and dispersion through a prism can be determined by tracing a sample ray through the element and using Snell's law at each interface.
Such dispersion of light in glass or water underlies the origin of rainbows and other optical phenomena, in which different wavelengths appear as different colors. In optical instruments, dispersion leads to chromatic aberration ; a color-dependent blurring that sometimes is the resolution-limiting effect.
The Kramers–Heisenberg dispersion formula is an expression for the cross section for scattering of a photon by an atomic electron. It was derived before the advent of quantum mechanics by Hendrik Kramers and Werner Heisenberg in 1925, [ 1 ] based on the correspondence principle applied to the classical dispersion formula for light.
The theory of light-matter interaction on which Cauchy based this equation was later found to be incorrect. In particular, the equation is only valid for regions of normal dispersion in the visible wavelength region. In the infrared, the equation becomes inaccurate, and it cannot represent regions of anomalous dispersion. Despite this, its ...
For common optical glasses, the refractive index calculated with the three-term Sellmeier equation deviates from the actual refractive index by less than 5×10 −6 over the wavelengths' range [5] of 365 nm to 2.3 μm, which is of the order of the homogeneity of a glass sample. [6]
Dispersion occurs when different frequencies of light have different phase velocities, due either to material properties (material dispersion) or to the geometry of an optical waveguide (waveguide dispersion). The most familiar form of dispersion is a decrease in index of refraction with increasing wavelength, which is seen in most transparent ...
For example, the higher dispersion flint glasses have relatively small Abbe numbers < whereas the lower dispersion crown glasses have larger Abbe numbers. Values of V d {\displaystyle V_{\mathsf {d}}} range from below 25 for very dense flint glasses, around 34 for polycarbonate plastics, up to 65 for common crown glasses, and 75 to 85 for some ...