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Such Zinc electroplating or Zinc alloy electroplating maintains a dominant position among other electroplating process options, based upon electroplated tonnage per annum. According to the International Zinc Association, more than 5 million tons are used yearly for both hot dip galvanizing and electroplating. [ 1 ]
Simplified diagram for electroplating copper (orange) on a conductive object (the cathode, "Me", gray). The electrolyte is a solution of copper sulfate, CuSO 4 in sulfuric acid. A copper anode is used to replenish the electrolyte with copper cations Cu 2+ as they are plated out at the cathode.
Hot-dip handrail galvanized crystalline surface Zinc sacrificial anode. Zinc is most commonly used as an anti-corrosion agent, [122] and galvanization (coating of iron or steel) is the most familiar form. In 2009 in the United States, 55% or 893,000 tons of the zinc metal was used for galvanization. [121]
Certain metals, such as zinc, may become embrittled from the hydrogen gas which is evolved at the cathode. The anodic process avoids this effect since oxygen is being generated at the anode. The major advantages that are normally touted for the cathodic processes are: Higher levels of corrosion protection are possible.
Bethanization is a process patented by the Bethlehem Steel Company to protect steel from corrosion by plating it with zinc, [1] a process similar to electrogalvanization.In advertising materials, Bethlehem Steel claimed the process was more effective than hot dip galvanization, the most common means of using zinc to protect steel.
Galvanizing with zinc protects the steel base metal by sacrificial anodic action. Cathodic protection uses one or more sacrificial anodes made of a metal which is more active than the protected metal. Alloys of metals commonly used for sacrificial anodes include zinc, magnesium, and aluminium. This approach is commonplace in water heaters and ...
The difference can be measured as a difference in voltage potential: the less noble metal is the one with a lower (that is, more negative) electrode potential than the nobler one, and will function as the anode (electron or anion attractor) within the electrolyte device functioning as described above (a galvanic cell).
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]
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