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Trimethyl orthoformate (TMOF) is the organic compound with the formula HC(OCH 3) 3. A colorless liquid, it is the simplest orthoester. It is a reagent used in organic synthesis for the formation of methyl ethers. [3] The product of reaction of an aldehyde with trimethyl orthoformate is an acetal.
CH 3 SiCl 3 + 3 CH 3 OH → CH 3 Si(OCH 3) 3 + 3 HCl. Alcoholysis of alkylchlorosilanes typically proceeds via an S N 2 mechanism. Inversion of the configuration is favored during nucleophilic attack when displacing good leaving groups, such as chloride. [3] In contrast, displacement of poor leaving groups, such as alkoxide, retention is ...
In nature, methoxy groups are found on nucleosides that have been subjected to 2′-O-methylation, for example in variations of the 5′-cap structure known as cap-1 and cap-2. They are also common substituents in O -methylated flavonoids , whose formation is catalyzed by O-methyltransferases that act on phenols , such as catechol- O -methyl ...
P(OCH 3) 3 → CH 3 P(O)(OCH 3) 2. As a ligand, trimethyl phosphite has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex Ni(P(OMe) 3) 4 (m.p. 108 °C). [4] The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The ...
Trimethyl borate is the organoboron compound with the formula B(OCH 3) 3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. [1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). [2]
Cyclooctadiene iridium methoxide dimer is an organoiridium compound with the formula Ir 2 (OCH 3) 2 (C 8 H 12) 2, where C 8 H 12 is the diene 1,5-cyclooctadiene. It is a yellow solid that is soluble in organic solvents. The complex is used as a precursor to other iridium complexes, some of which are used in homogeneous catalysis. [1]
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
To relate an octahedral fragment, ML n, where M has a d x electron configuration to a square planar analogous fragment, the formula ML n−2 where M has a d x+2 electron configuration should be followed. Further examples of the isolobal analogy in various shapes and forms are shown in figure 8.