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The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
However this assumption is often not justified, since the values of apparent molar properties of a component may be quite different from its molar properties in the pure state. For instance, the volume of a solution containing two components identified [ a ] as solvent and solute is given by
For a given solute-solvent mass ratio, all colligative properties are inversely proportional to solute molar mass. Measurement of colligative properties for a dilute solution of a non-ionized solute such as urea or glucose in water or another solvent can lead to determinations of relative molar masses , both for small molecules and for polymers ...
The properties of ideal solutions can be calculated by the linear combination of the properties of its components. If both solute and solvent exist in equal quantities (such as in a 50% ethanol, 50% water solution), the concepts of "solute" and "solvent" become less relevant, but the substance that is more often used as a solvent is normally ...
Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
This last partial derivative is the same as ¯, the partial molar Gibbs free energy. This means that the partial molar Gibbs free energy and the chemical potential, one of the most important properties in thermodynamics and chemistry, are the same quantity.
K b, the ebullioscopic constant, which is dependent on the properties of the solvent. It can be calculated as K b = RT b 2 M/ΔH v, where R is the gas constant, and T b is the boiling temperature of the pure solvent [in K], M is the molar mass of the solvent, and ΔH v is the heat of vaporization per mole of the solvent.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.