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A monomer (/ ˈ m ɒ n ə m ər / MON-ə-mər; mono-, "one" + -mer, "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization.
In chemistry, functionality is the presence of functional groups in a molecule. A monofunctional molecule possesses one functional group, a bifunctional (or difunctional) two, a trifunctional three, and so forth. In organic chemistry (and other fields of chemistry), a molecule's functionality has a decisive influence on its reactivity.
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
Another method of achieving the desired molecular weight is by addition of a small amount of monofunctional monomer, a monomer with only one functional group. The monofunctional monomer, often referred to as a chain stopper, controls and limits the polymerization of bifunctional monomers because the growing polymer yields chain ends devoid of ...
The molecular mass of the chain is just the product nM R. Other than monodisperse polymers, there is normally a molar mass distribution caused by chains of different length. In copolymers there are two or more types of repeat unit, which may be arranged in alternation, or at random, or in other more complex patterns.
According to the standard IUPAC definition, the term macromolecule as used in polymer science refers only to a single molecule. For example, a single polymeric molecule is appropriately described as a "macromolecule" or "polymer molecule" rather than a "polymer," which suggests a substance composed of macromolecules. [8]
A polymer (/ ˈ p ɒ l ɪ m ər / [4] [5]) is a substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeating subunits derived from one or more species of monomers. [6]
Following this usage, a protomer consists of a least two different proteins chains. In current literature of structural biology, the term is commonly also applied to the smallest unit of homo-oligomers, avoiding the term "monomer". In chemistry, a so-called protomer is a molecule which displays tautomerism due to position of a proton. [2] [3]