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Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
In this section we show that the order statistics of the uniform distribution on the unit interval have marginal distributions belonging to the beta distribution family. We also give a simple method to derive the joint distribution of any number of order statistics, and finally translate these results to arbitrary continuous distributions using ...
Before this point in time, a gradual variation in the concentration of A occurs along an axis, designated x, which joins the original compartments. This variation, expressed mathematically as -dC A /dx, where C A is the concentration of A. The negative sign arises because the concentration of A decreases as the distance x increases.
The distribution of values in decreasing order of rank is often of interest when values vary widely in scale; this is the rank-size distribution (or rank-frequency distribution), for example for city sizes or word frequencies. These often follow a power law. Some ranks can have non-integer values for tied data values.
A solution containing an aqua ion does not have the long-range order that would be present in a crystal containing the same ion, but there is short-range order. X-ray diffraction on solutions yields a radial distribution function from which the coordination number of the metal ion and metal-oxygen distance may be derived. With aqua ions of high ...
In the phenomenological approach, diffusion is the movement of a substance from a region of high concentration to a region of low concentration without bulk motion. According to Fick's laws, the diffusion flux is proportional to the negative gradient of concentrations. It goes from regions of higher concentration to regions of lower concentration.
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The standard state for a dilute solution is also defined in terms of infinite-dilution behavior. Although the standard concentration c° is taken to be 1 mol/L by convention, the standard state is a hypothetical solution of 1 mol/L in which the solute has its limiting infinite-dilution properties. This has the effect that all non-ideal behavior ...