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This method enables precise measurements at room temperature because it is insensitive to doppler broadening. Absorption spectroscopy measures the doppler-broadened transition, so the atoms must be cooled to millikelvin temperatures to achieve the same sensitivity as saturated absorption spectroscopy.
Doppler spectroscopy (also known as the radial-velocity method, or colloquially, the wobble method) is an indirect method for finding extrasolar planets and brown dwarfs from radial-velocity measurements via observation of Doppler shifts in the spectrum of the planet's parent star. As of November 2022, about 19.5% of known extrasolar planets ...
A particular case is the thermal Doppler broadening due to the thermal motion of the particles. Then, the broadening depends only on the frequency of the spectral line, the mass of the emitting particles, and their temperature , and therefore can be used for inferring the temperature of an emitting (or absorbing) body being spectroscopically ...
For atoms in the gas phase the principal effects are Doppler and pressure broadening. Lines are relatively sharp on the scale of measurement so that applications such as atomic absorption spectroscopy (AAS) and Inductively coupled plasma atomic emission spectroscopy (ICP) are used for elemental analysis. Atoms also have distinct x-ray spectra ...
The Doppler temperature is the minimum temperature achievable with Doppler cooling. When a photon is absorbed by an atom counter-propagating to the light source, its velocity is decreased by momentum conservation. When the absorbed photon is spontaneously emitted by the excited atom, the atom receives a momentum kick in a random direction.
In spectroscopy, the Dicke effect, also known as Dicke narrowing or sometimes collisional narrowing, named after Robert H. Dicke, refers to narrowing of the Doppler broadening of a spectral line due to collisions the emitting species (usually an atom or a molecule) experiences with other particles. [1] [2]
The Doppler parameters of Lyman-alpha forest absorption lines are in the range 10–100 km s −1, with a median value around = that decrease with redshift (Kim et al. 1997). Analyses of the HST / COS dataset of low-redshift quasars gives a median b {\displaystyle b} parameter of around 33 k m s − 1 {\displaystyle 33\ \mathrm {km\ s} ^{-1 ...
Each of these mechanisms can act in isolation or in combination with others. Assuming each effect is independent, the observed line profile is a convolution of the line profiles of each mechanism. For example, a combination of the thermal Doppler broadening and the impact pressure broadening yields a Voigt profile.
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