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Electron atomic and molecular orbitals A Bohr diagram of lithium. In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. [1]
The chart of orbitals (left) is arranged by increasing energy (see Madelung rule). Atomic orbits are functions of three variables (two angles, and the distance r from the nucleus). These images are faithful to the angular component of the orbital, but not entirely representative of the orbital as a whole.
Each chemical element has a unique atomic number (Z— for "Zahl", German for "number") representing the number of protons in its nucleus. [4] Each distinct atomic number therefore corresponds to a class of atom: these classes are called the chemical elements. [5] The chemical elements are what the periodic table classifies and organizes.
The f-orbital electrons are less active in the chemistry of the period 6 f-block elements, although they do make some contribution; [5] these are rather similar to each other. They are more active in the early period 7 f-block elements, where the energies of the 5f, 7s, and 6d shells are quite similar; consequently these elements tend to show ...
Orbital elements are the parameters required to uniquely identify a specific orbit. In celestial mechanics these elements are considered in two-body systems using a Kepler orbit . There are many different ways to mathematically describe the same orbit, but certain schemes, each consisting of a set of six parameters, are commonly used in ...
This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state.
In chemical reactions, orbital wavefunctions are modified, i.e. the electron cloud shape is changed, according to the type of atoms participating in the chemical bond. It was introduced in 1929 by Sir John Lennard-Jones with the description of bonding in the diatomic molecules of the first main row of the periodic table, but had been used ...
The orbital wave functions are positive in the red regions and negative in the blue. The right column shows virtual MO's which are empty in the ground state, but may be occupied in excited states. In chemistry, a molecular orbital (/ ɒr b ə d l /) is a mathematical function describing the location and wave-like behavior of an electron in a ...