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  2. Gibbs–Donnan effect - Wikipedia

    en.wikipedia.org/wiki/Gibbs–Donnan_effect

    For example, the large anionic proteins in blood plasma are not permeable to capillary walls. Because small cations are attracted, but are not bound to the proteins, small anions will cross capillary walls away from the anionic proteins more readily than small cations. Thus, some ionic species can pass through the barrier while others cannot.

  3. Neighbouring group participation - Wikipedia

    en.wikipedia.org/wiki/Neighbouring_group...

    In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.

  4. Kröger–Vink notation - Wikipedia

    en.wikipedia.org/wiki/Kröger–Vink_Notation

    Assume the chemical composition is AX, with A being the cation and X being the anion. (The following assumes that X is a diatomic gas such as oxygen and therefore cation A has a +2 charge. Note that materials with this defect structure are often used in oxygen sensors.) In the reduced n-type, there are excess cations on the interstitial sites: A ×

  5. Phosphoric acids and phosphates - Wikipedia

    en.wikipedia.org/wiki/Phosphoric_acids_and...

    Branched polyphosphoric acids give similarly branched polyphosphate anions. The simplest example of this is triphosphono phosphate [OP(OPO 3) 3] 9− and its partially dissociated versions. The general formula for such (non-cyclic) polyphosphate anions, linear or branched, is [H n+2−k P n O 3n+1] k−, where the charge k may vary from 1 to n + 2.

  6. Nursing diagnosis - Wikipedia

    en.wikipedia.org/wiki/Nursing_diagnosis

    A nursing diagnosis may be part of the nursing process and is a clinical judgment about individual, family, or community experiences/responses to actual or potential health problems/life processes. Nursing diagnoses foster the nurse's independent practice (e.g., patient comfort or relief) compared to dependent interventions driven by physician ...

  7. Anion gap - Wikipedia

    en.wikipedia.org/wiki/Anion_gap

    Calculating the anion gap is clinically useful because it helps in the differential diagnosis of a number of disease states. [citation needed] The total number of cations (positive ions) should be equal to the total number of anions (negative ions), so that the overall electrical charge is neutral.

  8. Heteropolymetalate - Wikipedia

    en.wikipedia.org/wiki/Heteropolymetalate

    They are usually colorless to orange, diamagnetic anions. For most heteropolymetalates the W, Mo, or V, is complemented by main group oxyanions phosphate and silicate . Many exceptions to these general statements exist, and the class of compounds includes hundreds of examples.

  9. Valence (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Valence_(chemistry)

    For example, the Cs + cation is a univalent or monovalent cation, whereas the Ca 2+ cation is a divalent cation, and the Fe 3+ cation is a trivalent cation. Unlike Cs and Ca, Fe can also exist in other charge states, notably 2+ and 4+, and is thus known as a multivalent (polyvalent) ion. [ 15 ]