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The primitive unit cell for the body-centered cubic crystal structure contains several fractions taken from nine atoms (if the particles in the crystal are atoms): one on each corner of the cube and one atom in the center. Because the volume of each of the eight corner atoms is shared between eight adjacent cells, each BCC cell contains the ...
This structure is often confused for a body-centered cubic structure because the arrangement of atoms is the same. However, the caesium chloride structure has a basis composed of two different atomic species. In a body-centered cubic structure, there would be translational symmetry along the [111] direction.
Both arrangements produce a face-centered cubic lattice – with different orientation to the ground. Hexagonal close-packing would result in a six-sided pyramid with a hexagonal base. Collections of snowballs arranged in pyramid shape. The front pyramid is hexagonal close-packed and rear is face-centered cubic.
This type of structural arrangement is known as cubic close packing (ccp). The unit cell of a ccp arrangement of atoms is the face-centered cubic (fcc) unit cell. This is not immediately obvious as the closely packed layers are parallel to the {111} planes of the fcc unit cell. There are four different orientations of the close-packed layers.
A close packed unit cell, both face-centered cubic and hexagonal close packed, can form two different shaped holes. Looking at the three green spheres in the hexagonal packing illustration at the top of the page, they form a triangle-shaped hole. If an atom is arranged on top of this triangular hole it forms a tetrahedral interstitial hole.
Slip in body-centered cubic (bcc) crystals occurs along the plane of shortest Burgers vector as well; however, unlike fcc, there are no truly close-packed planes in the bcc crystal structure. Thus, a slip system in bcc requires heat to activate.
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(This is the unique body-centered cubic packing of edge-length spheres of the tesseractic honeycomb.) Just outside this shell of kissing 3-spheres of diameter 1 is another less dense shell of 24 non-kissing 3-spheres of diameter 1; they are centered in the adjacent 24-cells with which the central 24-cell shares an octahedral facet.