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Citric acid also dissolves in absolute (anhydrous) ethanol (76 parts of citric acid per 100 parts of ethanol) at 15 °C. It decomposes with loss of carbon dioxide above about 175 °C. Citric acid is a triprotic acid, with pK a values, extrapolated to zero ionic strength, of 3.128, 4.761, and 6.396 at 25 °C. [21]
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Ethanol is a neutral molecule and the pH of a solution of ethanol in water is nearly 7.00. Ethanol can be quantitatively converted to its conjugate base, the ethoxide ion (CH 3 CH 2 O −), by reaction with an alkali metal such as sodium: [78] 2 CH 3 CH 2 OH + 2 Na → 2 CH 3 CH 2 ONa + H 2. or a very strong base such as sodium hydride: CH 3 CH ...
Triethyl citrate is an ester of citric acid. It is a colorless, odorless liquid used as a food additive, emulsifier and solvent (E number E1505) [4] to stabilize foams, especially as whipping aid for egg white. [5] It is also used in pharmaceutical coatings and plastics. [6]
Under alcoholic conditions, the citric acid cycle is stalled by the oversupply of NADH derived from ethanol oxidation. The resulting backup of acetate shifts the reaction equilibrium for acetaldehyde dehydrogenase back towards acetaldehyde. Acetaldehyde subsequently accumulates and begins to form covalent bonds with cellular macromolecules ...
Monosodium citrate, more correctly, sodium dihydrogen citrate (Latin: natrium citricum acidulatum), is an acid salt of citric acid. Disodium citrate and trisodium citrate are also known. It can be prepared by partial neutralisation of citric acid [3] with an aqueous solution of sodium bicarbonate or carbonate. It has a slightly acidic taste. [3]
Solubility: slightly soluble in methanol, ethanol insoluble in acetone, benzene: ... which is an intermediate of the citric acid cycle and can be readily incorporated ...