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The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group [1] (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can be added to amines under aqueous conditions using di- tert -butyl dicarbonate in the presence of a base such as sodium hydroxide :
pelargonic acid 1-octanecarboxylic acid: CH 3 (CH 2) 7 COOH benzene-1,3,5-tricarboxylic acid: trimesic acid: C 6 H 3 (COOH) 3 (E)-3-phenylprop-2-enoic acid: cinnamic acid trans-cinnamic acid phenylacrylic acid cinnamylic acid 3-phenylacrylic acid (E)-cinnamic acid benzenepropenoic acid isocinnamic acid: C 6 H 5 CH=CHCOOH
A synthetic derivative, 9-methyl-β-carboline, has shown neuroprotective effects including increased expression of neurotrophic factors and enhanced respiratory chain activity. [ 10 ] [ 11 ] This derivative has also been shown to enhance cognitive function , [ 12 ] increase dopaminergic neuron count and facilitate synaptic and dendritic ...
Di-tert-butyl dicarbonate is a reagent widely used in organic synthesis. [1] Since this compound can be regarded formally as the acid anhydride derived from a tert-butoxycarbonyl (Boc) group, it is commonly referred to as Boc anhydride. This pyrocarbonate reacts with amines to give N-tert-butoxycarbonyl or so-called Boc
Their unique feature is that they are capable of forming reversible covalent complexes with sugars, amino acids, hydroxamic acids, etc. (molecules with vicinal, (1,2) or occasionally (1,3) substituted Lewis base donors (alcohol, amine, carboxylate)). The pK a of a boronic acid is ~9, but they can form tetrahedral boronate complexes with pK a ~7.
Carboxylate ion Acrylate ion. In organic chemistry, a carboxylate is the conjugate base of a carboxylic acid, RCOO − (or RCO − 2). It is an anion, an ion with negative charge. Carboxylate salts are salts that have the general formula M(RCOO) n, where M is a metal and n is 1, 2,....
Naphthoylindoles: Any compound containing a 3-(1-naphthoyl)indole structure with substitution at the nitrogen atom of the indole ring by an alkyl, haloalkyl, alkenyl, cycloalkylmethyl, cycloalkylethyl, 1-(N-methyl-2-piperidinyl)methyl, or 2-(4-morpholinyl)ethyl group, whether or not further substituted in the indole ring to any extent and whether or not substituted in the naphthyl ring to any ...
Calligonine ((1R)-1-methyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole) Calligonine is a major alkaloid constituent of the roots of Calligonum minimum and the bark of Elaeagnus angustifolia . When taken internally, it has the effect of substantially lowering blood pressure for an extended period of time, similar to reserpine .