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For example, the nitrogen atom ground state has three unpaired electrons of parallel spin, so that the total spin is 3/2 and the multiplicity is 4. The lower energy and increased stability of the atom arise because the high-spin state has unpaired electrons of parallel spin, which must reside in different spatial orbitals according to the Pauli ...
These "new" states could violate the Pauli exclusion principle. The aim of VIP2 is to search for new quantum states, which have a symmetric component in an otherwise antisymmetric state. These non-Paulian states can be identified by the characteristic X-rays emitted during Pauli exclusion principle—prohibited atomic transitions to the ground ...
To test the Pauli exclusion principle for the helium atom, Gordon Drake [11] carried out very precise calculations for hypothetical states of the He atom that violate it, which are called paronic states. Later, K. Deilamian et al. [12] used an atomic beam spectrometer to search for the paronic state 1s2s 1 S 0 calculated by Drake.
In chemistry and physics, the exchange interaction is a quantum mechanical constraint on the states of indistinguishable particles.While sometimes called an exchange force, or, in the case of fermions, Pauli repulsion, its consequences cannot always be predicted based on classical ideas of force. [1]
Following the Pauli exclusion principle, there can be only one fermion occupying each quantum state. In a degenerate gas, all quantum states are filled up to the Fermi energy. Most stars are supported against their own gravitation by normal thermal gas pressure, while in white dwarf stars the supporting force comes from the degeneracy pressure ...
The rule of mutual exclusion in molecular spectroscopy relates the observation of molecular vibrations to molecular symmetry. It states that no normal modes can be both Infrared and Raman active in a molecule that possesses a center of symmetry .
In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.
Search-match algorithms compare selected test reflections of an unknown crystal phase with entries in the database. Intensity-driven algorithms utilize the three most intense lines (so-called ‘Hanawalt search’), while d -spacing-driven algorithms are based on the eight to ten largest d -spacings (so-called ‘Fink search’).