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A derivative of trifluorotoluene, 3-aminobenzotrifluoride, is the precursor to the herbicide fluometuron. [3] It is synthesized via nitration followed by reduction to meta-H 2 NC 6 H 4 CF 3. This aniline is then converted to the urea. Flumetramide (6-[4-(trifluoromethyl)phenyl]morpholin-3-one), a skeletal muscle relaxant, is also prepared from ...
Trichlorobenzene (TCB) may refer to any of three isomeric chlorinated derivatives of benzene with the molecular formula C 6 H 3 Cl 3. They differ by the positions of the chlorine atoms around the ring: 1,2,3-Trichlorobenzene; 1,2,4-Trichlorobenzene; 1,3,5-Trichlorobenzene
They have the formula C 6 H 6–n F n, where n = 1–6 is the number of fluorine atoms. Depending on the number of fluorine substituents, there may be several constitutional isomers possible. [1] Monofluorobenzene; Difluorobenzene. 1,2-Difluorobenzene; 1,3-Difluorobenzene; 1,4-Difluorobenzene; Trifluorobenzene. 1,2,3-Trifluorobenzene; 1,2,4 ...
The LD50 (oral, rats) is 756 mg/kg. Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday.
This is readily removed by vigorously stirring the commercial material with a concentrated aqueous solution of K 3 PO 4 and K 2 HPO 4 in a 1:1 molar ratio for 96 hours. This treatment, followed by removal of the aqueous layer and distillation from P 2 O 5, gives a product that contains >99 mol % NfF with near quantitative recovery. [3]
Benzenesulfonyl chloride is an organosulfur compound with the formula C 6 H 5 SO 2 Cl. It is a colourless viscous oil that dissolves in organic solvents, but reacts with compounds containing reactive N-H and O-H bonds. It is mainly used to prepare sulfonamides and sulfonate esters by reactions with amines and alcohols, respectively. [1]
The sulfonyl functional group (RS(O) 2 R') has become an important electron-withdrawing group for modern organic chemistry. α-Sulfonyl carbanions may be used as nucleophiles in alkylation reactions, Michael-type additions, and other processes. [3] After having served their synthetic purpose, sulfonyl groups are often removed.
With a K a = 5 × 10 14, pK a = −14.7 ± 2.0, [1] triflic acid qualifies as a superacid. It owes many of its useful properties to its great thermal and chemical stability. Both the acid and its conjugate base CF 3 SO − 3, known as triflate, resist oxidation/reduction reactions, whereas many strong acids are oxidizing, such as perchloric or ...