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Phosphine appears to be mainly a redox toxin, causing cell damage by inducing oxidative stress and mitochondrial dysfunction. [35] Resistance in insects is caused by a mutation in a mitochondrial metabolic gene. [29] Phosphine can be absorbed into the body by inhalation. The main target organ of phosphine gas is the respiratory tract. [36]
Phosphine is produced by hydrolysis of calcium phosphide, Ca 3 P 2. Unlike ammonia, phosphine is oxidised by air. Phosphine is also far less basic than ammonia. Other phosphines are known which contain chains of up to nine phosphorus atoms and have the formula P n H n+2. [17] The highly flammable gas diphosphine (P 2 H 4) is an analogue of ...
Bubbles of methane, created by methanogens, that are present in the marsh, more commonly known as marsh gas. Marsh gas, also known as swamp gas or bog gas, is a mixture primarily of methane and smaller amounts of hydrogen sulfide, carbon dioxide, and trace phosphine that is produced naturally within some geographical marshes, swamps, and bogs.
Phosgene is an organic chemical compound with the formula COCl 2.It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. [7]
The latter is a common feature of the chemistry of phosphorus. As a result, the lone pair of trimethylphosphine has predominantly s-character as is the case for phosphine, PH 3. [10] Tertiary phosphines are pyramidal. When the organic substituents all differ, the phosphine is chiral and
Going down the group, to phosphane (phosphine), arsane (arsine), stibane (stibine), and finally bismuthane (bismuthine), each pnictogen hydride becomes progressively less stable (more unstable), more toxic, and has a smaller hydrogen-hydrogen angle (from 107.8° in ammonia [6] to 90.48° in bismuthane). [7] (Also, technically, only ammonia and ...
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
Organophosphorus chemistry is the scientific study of the synthesis and properties of organophosphorus compounds, which are organic compounds containing phosphorus. [1] They are used primarily in pest control as an alternative to chlorinated hydrocarbons that persist in the environment.