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Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. [1]
Photocatalysts must conform to several key principles in order to be considered effective at water splitting. A key principle is that H 2 and O 2 evolution should occur in a stoichiometric 2:1 ratio; significant deviation could be due to a flaw in the experimental setup and/or a side reaction, neither of which indicate a reliable photocatalyst for water splitting.
For example, at 2,200 °C (2,470 K; 3,990 °F) about three percent of all H 2 O are dissociated into various combinations of hydrogen and oxygen atoms, mostly H, H 2, O, O 2, and OH. Other reaction products like H 2 O 2 or HO 2 remain minor. At the very high temperature of 3,000 °C (3,270 K; 5,430 °F) more than half of the water molecules are ...
Photosynthesis (/ ˌ f oʊ t ə ˈ s ɪ n θ ə s ɪ s / FOH-tə-SINTH-ə-sis) [1] is a system of biological processes by which photosynthetic organisms, such as most plants, algae, and cyanobacteria, convert light energy, typically from sunlight, into the chemical energy necessary to fuel their metabolism.
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a photocatalyst, the excited state of which "repeatedly interacts with the reaction partners forming reaction intermediates and regenerates itself after each cycle of such interactions."
The reaction for the aerobic respiration is essentially the reverse of photosynthesis, except that now there is a large release of chemical energy which is stored in ATP molecules (up to 38 ATP molecules are formed from one molecule of glucose and 6 O 2 molecules). The simplified version of this reaction is: C 6 H 12 O 6 + 6 O 2 → 6 CO 2 + 6 H
The active site of the OEC consists of a cluster of manganese and calcium with the formula Mn 4 Ca 1 O x Cl 1–2 (HCO 3) y. This cluster is bound to D 1 and CP 43 subunits and stabilized by peripheral membrane proteins. Many characteristics of it have been examined by flash photolysis experiments, electron paramagnetic resonance (EPR), and X ...
Photosystem II (or water-plastoquinone oxidoreductase) is the first protein complex in the energy-dependent reactions of oxygenic photosynthesis. It is located in the thylakoid membrane of plants , algae , and cyanobacteria .
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