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  2. Valence (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Valence_(chemistry)

    In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one, can be substituted for hydrogen in many compounds. Phosphorus has a valence 3 in phosphine (PH 3) and a valence of 5 in phosphorus ...

  3. Valence electron - Wikipedia

    en.wikipedia.org/wiki/Valence_electron

    An atom with one or two electrons fewer than a closed shell is reactive due to its tendency either to gain the missing valence electrons and form a negative ion, or else to share valence electrons and form a covalent bond. Similar to a core electron, a valence electron has the ability to absorb or release energy in the form of a photon.

  4. Equivalent (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Equivalent_(chemistry)

    The "hydrogen ion" and the "electron" in these examples are respectively called the "reaction units." By this definition, the number of equivalents of a given ion in a solution is equal to the number of moles of that ion multiplied by its valence. For example, consider a solution of 1 mole of NaCl and 1 mole of CaCl 2. The solution has 1 mole ...

  5. 18-electron rule - Wikipedia

    en.wikipedia.org/wiki/18-electron_rule

    Compounds that obey the 18-electron rule are typically "exchange inert". Examples include [Co(NH 3) 6]Cl 3, Mo(CO) 6, and [Fe(CN) 6] 4−. In such cases, in general ligand exchange occurs via dissociative substitution mechanisms, wherein the rate of reaction is determined by the rate of dissociation of a ligand. On the other hand, 18-electron ...

  6. Octet rule - Wikipedia

    en.wikipedia.org/wiki/Octet_rule

    The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule.. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.

  7. Chloride - Wikipedia

    en.wikipedia.org/wiki/Chloride

    A chloride ion (diameter 167 pm) is much larger than a chlorine atom (diameter 99 pm). The chlorine atom's hold on the valence shell is weaker because the chloride anion has one more electron than it does. [5] The ion is colorless and diamagnetic.

  8. Chlorate - Wikipedia

    en.wikipedia.org/wiki/Chlorate

    In this reaction, chlorine undergoes disproportionation, both reduction and oxidation. Chlorine, oxidation number 0, forms chloride Cl − (oxidation number −1) and chlorate(V) ClO − 3 (oxidation number +5). The reaction of cold aqueous metal hydroxides with chlorine produces the chloride and hypochlorite (oxidation number +1) instead ...

  9. Oxidation state - Wikipedia

    en.wikipedia.org/wiki/Oxidation_state

    Additional postulates and their ranking may expand the range of compounds to fit a textbook's scope. As an example, one postulatory algorithm from many possible; in a sequence of decreasing priority: An element in a free form has OS = 0. In a compound or ion, the sum of the oxidation states equals the total charge of the compound or ion.