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Iodine trichloride, which exists in the solid state as the planar dimer I 2 Cl 6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
Iodine monobromide is an interhalogen compound with the formula IBr. It is a dark red solid that melts near room temperature. [1] Like iodine monochloride, IBr is used in some types of iodometry. It serves as a source of I +. Its Lewis acid properties are compared with those of ICl and I 2 in the ECW model. It can form CT adducts with Lewis ...
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This is an accepted version of this page This is the latest accepted revision, reviewed on 16 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
Silver bromide (AgBr). Nearly all elements in the periodic table form binary bromides. The exceptions are decidedly in the minority and stem in each case from one of three causes: extreme inertness and reluctance to participate in chemical reactions (the noble gases, with the exception of xenon in the very unstable XeBr 2; extreme nuclear instability hampering chemical investigation before ...
These methods work best when the bromide product is stable to hydrolysis; otherwise, the possibilities include high-temperature oxidative bromination of the element with bromine or hydrogen bromide, high-temperature bromination of a metal oxide or other halide by bromine, a volatile metal bromide, carbon tetrabromide, or an organic bromide.
It can be made from the elements at low temperature, or from iodine pentoxide and hydrogen chloride. It reacts with many metal chlorides to form tetrachloroiodides (ICl − 4), and hydrolyses in water. The molecule is a planar dimer (ICl 3) 2, with each iodine atom surrounded by four chlorine atoms. Iodine tribromide (IBr 3) is a dark brown liquid.
The first two compounds may also be produced in water – astatine reacts with iodine/iodide solution to form AtI, whereas AtBr requires (aside from astatine) an iodine/iodine monobromide/bromide solution. The excess of iodides or bromides may lead to AtBr − 2 and AtI − 2 ions, [4] or in a chloride solution, they may produce species like ...