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As a result of these assumptions, a conversion slightly higher than that predicted by the Flory–Stockmayer Theory is commonly needed to actually create a polymer gel. Since steric hindrance effects prevent each functional group from being equally reactive and intramolecular reactions do occur, the gel forms at slightly higher conversion. [5]
It is referred to as the Purple Book. It was published in 1991 (ISBN 0-63202-8475) by Blackwell Science. The author of this book is W.V. Metanomski. The expansion of this book named Compendium of Polymer Terminology and Nomenclature: IUPAC Recommendations, 2008 was published by the Royal Society of Chemistry in 2009 (ISBN 978 0 85404 491 7).
Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing.
"Molecular Basis of the Structure and Behavior of Polymers, Part II: Chemistry and Structure of Macromolecules—Design of Polymer Chains" (PDF). EPFL.ch (polymer chemistry course materils). Lausanne, Switzerland: Laboratory of Polymers and Biomaterials, Dept. of Chemistry, Ecole Polytechnique Federale de Lausanne (EPFL).
Non-linear polymers and copolymers, and polymer assemblies are named using the italicized qualifiers in Table 2. [5] The qualifier, such as branch, is used as a prefix (P) when naming a (co)polymer, or as a connective (C), e.g., comb, between two polymer names.
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry ...
Another possibility is chain transfer to a second polymer molecule, result in the formation of a product macromolecule with a branched structure. In this case the growing chain takes an atom X from a second polymer chain whose growth had been completed. The growth of the first polymer chain is completed by the transfer of atom X.
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