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In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon –carbon double bond. [ 1 ] The double bond may be internal or in the terminal position. Terminal alkenes are also known as α-olefins. The International Union of Pure and Applied Chemistry (IUPAC) recommends using the name "alkene" only for acyclic hydrocarbons ...
Terminal alkynes, like acetylene itself, are mildly acidic, with pK a values of around 25. They are far more acidic than alkenes and alkanes, which have pK a values of around 40 and 50, respectively. The acidic hydrogen on terminal alkynes can be replaced by a variety of groups resulting in halo-, silyl-, and alkoxoalkynes.
Alkane. In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. [1] Alkanes have the general chemical formula CnH2n+2.
Dehalogenation. In organic chemistry, dehalogenation is a set of chemical reactions that involve the cleavage of carbon - halogen bonds; as such, it is the inverse reaction of halogenation. Dehalogenations come in many varieties, including defluorination (removal of fluorine), dechlorination (removal of chlorine), debromination (removal of ...
Haloalkane. Tetrafluoroethane (a haloalkane) is a colorless liquid that boils well below room temperature (as seen here) and can be extracted from common canned air canisters by simply inverting them during use. The haloalkanes (also known as halogenoalkanes or alkyl halides) are alkanes containing one or more halogen substituents. [1]
The double bond of an alpha olefin is between the #1 and #2 (IUPAC) or α and β (common) carbon atoms. In organic chemistry, terminal alkenes (alpha-olefins, α-olefins, or 1-alkenes) are a family of organic compounds which are alkenes (also known as olefins) with a chemical formula CxH2x, distinguished by having a double bond at the primary ...
In organic chemistry, hydroformylation, also known as oxo synthesis or oxo process, is an industrial process for the production of aldehydes (R−CH=O) from alkenes (R2C=CR2). [1][2] This chemical reaction entails the net addition of a formyl group (−CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone ...
This can react with almost all alkenes and alkynes, including styrenes and alcohols. This is especially useful, as the unmodified Simmons-Smith is known to deprotonate alcohols. Unfortunately, as in Pathway B shown the intermediate can also react with the starting diazo compound, giving cis - or trans - 1,2-diphenylethene.