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On the other hand, if a chemical is a weak acid its conjugate base will not necessarily be strong. Consider that ethanoate, the conjugate base of ethanoic acid, has a base splitting constant (Kb) of about 5.6 × 10 −10, making it a weak base. In order for a species to have a strong conjugate base it has to be a very weak acid, like water.
Azanide is the IUPAC-sanctioned name for the anion NH − 2. The term is obscure; derivatives of NH − 2 are almost invariably referred to as amides, [1] [2] [3] despite the fact that amide also refers to the organic functional group – C(=O)−NR 2. The anion NH − 2 is the conjugate base of ammonia, so it is formed by the self-ionization ...
The conjugate base of phthalimide is potassium phthalimide. These anion can be alkylated to give N-alkylimides, which in turn can be degraded to release the primary amine. Strong nucleophiles, such as potassium hydroxide or hydrazine are used in the release step. Treatment of imides with halogens and base gives the N-halo derivatives
A conjugate base is formed when the acid is deprotonated by the base. In the image above, hydroxide acts as a base to deprotonate the carboxylic acid. The conjugate base is the carboxylate salt. In this case, hydroxide is a strong enough base to deprotonate the carboxylic acid because the conjugate base is more stable than the base because the ...
In coordination chemistry, the S N 1cB (conjugate base) mechanism describes the pathway by which many metal amine complexes undergo substitution, that is, ligand exchange. Typically, the reaction entails reaction of a polyamino metal halide with aqueous base to give the corresponding polyamine metal hydroxide: [ 1 ]
Structures of three kinds of amides: an organic amide (carboxamide), a sulfonamide, and a phosphoramide. In chemistry, the term amide (/ ˈ æ m aɪ d / or / ˈ æ m ɪ d / or / ˈ eɪ m aɪ d /) [1] [2] [3] is a compound with the functional group R n E(=O) x NR 2, where x is not zero, E is some element, and each R represents an organic group or hydrogen. [4]
2 Na + 2 NH 3 → 2 NaNH 2 + H 2. NaNH 2 is a salt-like material and as such, crystallizes as an infinite polymer. [5] The geometry about sodium is tetrahedral. [6] In ammonia, NaNH 2 forms conductive solutions, consistent with the presence of [Na(NH 3) 6] + and NH − 2 ions.
In acid–base chemistry, homoassociation (an IUPAC term) [2] is an association between a base and its conjugate acid through a hydrogen bond. [1] Most commonly, homoassociation leads to the enhancement of the acidity of an acid by itself. The effect is accentuated at high concentrations, i.e. the ionization of an acid varies nonlinearly with ...