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In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]
Helmholtz resonance, also known as wind throb, refers to the phenomenon of air resonance in a cavity, an effect named after the German physicist Hermann von Helmholtz. [1] This type of resonance occurs when air is forced in and out of a cavity (the resonance chamber ), causing the air inside to vibrate at a specific natural frequency .
To cause resonance, the phase of a sinusoidal wave after a round trip must be equal to the initial phase so the waves self-reinforce. The condition for resonance in a resonator is that the round trip distance, 2 d {\displaystyle 2d\,} , is equal to an integer number of wavelengths λ {\displaystyle \lambda \,} of the wave:
The global electromagnetic resonance phenomenon is named after physicist Winfried Otto Schumann who predicted it mathematically in 1952. Schumann resonances are the principal background in the part of the electromagnetic spectrum [2] from 3 Hz through 60 Hz [3] and appear as distinct peaks at extremely low frequencies around 7.83 Hz (fundamental), 14.3, 20.8, 27.3, and 33.8 Hz.
However, resonance can also be detrimental, leading to excessive vibrations or even structural failure in some cases. [3] All systems, including molecular systems and particles, tend to vibrate at a natural frequency depending upon their structure; this frequency is known as a resonant frequency or resonance frequency.
The term “resonance” relates to the use of this term in nuclear physics, where peaks in the dependence of a reaction cross section upon energy are called “resonances”. Similarly, a sharp increase (or decrease) in the reaction kinetics as a function of the average isotopic mass of a certain element is called here a resonance.
In experiment, the incident beam that produces resonance always has some spread of energy around a central value. Usually, that is a Gaussian/normal distribution.The resulting resonance shape in this case is given by the convolution of the Breit–Wigner and the Gaussian distribution,
The last version that is compatible with Windows 2000 is version 7.10. The last version that is compatible with Windows 9x is version 3.45. Starting with K-Lite version 10.0.0, 64-bit codecs were integrated into the regular K-Lite Codec Pack. Previously, a separate 64-bit edition of the pack was available for x64 editions of Windows. [10]