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Used in a more general sense, the term X,Y-acetal also refers to any functional group that consists of a carbon bearing two heteroatoms X and Y. For example, N,O-acetal refers to compounds of type R 1 R 2 C(OR)(NR' 2) (R,R' ≠ H) also known as a hemiaminal ether or Aminal, a.k.a. aminoacetal.
The example below depicts the acetalisation reaction of D-ribose 1. With acetone or 2,2-dimethoxypropane as the acetalisation reagent the reaction is under thermodynamic reaction control and results in the pentose 2. The latter reagent in itself is an acetal and therefore the reaction is actually a cross-acetalisation.
For example: ethanol, CH 3 −CH 2 −OH, is the product of the hydration reaction of ethene, CH 2 =CH 2, formed by the addition of H to one C and OH to the other C, and so can be considered as the hydrate of ethene. A molecule of water may be eliminated, for example, by the action of sulfuric acid.
The product, CH 3 CH(OCH 2 CH 3) 2, is formally named 1,1-diethoxyethane but is commonly referred to as "acetal". [39] This can cause confusion as "acetal" is more commonly used to describe compounds with the functional groups RCH(OR') 2 or RR'C(OR'') 2 rather than referring to this specific compound — in fact, 1,1-diethoxyethane is also ...
Lactose is a disaccharide found in animal milk. It consists of a molecule of D-galactose and a molecule of D-glucose bonded by beta-1-4 glycosidic linkage.. A carbohydrate (/ ˌ k ɑːr b oʊ ˈ h aɪ d r eɪ t /) is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula C m ...
As example, the flight-enabling pappus of the common dandelion achene undergoes binary morphing (opened or closed) of its whisker-like filaments, in unison with chorused responses of the remaining achenes. Pappus movement is controlled via a hygroscopic actuator in the apical plate, at the beak's top, the locus for all the achene's filaments.
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The direct oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an aldehyde hydrate (R−CH(OH) 2) by reaction with water before it can be further oxidized to the carboxylic acid. Mechanism of oxidation of primary alcohols to carboxylic acids via aldehydes and aldehyde hydrates