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In electrochemistry. In electrochemistry, concentration polarization denotes the part of the polarization of an electrolytic cell resulting from changes in the electrolyte concentration due to the passage of current through the electrode/solution interface. [ 1 ] Here polarization is understood as the shift of the electrochemical potential ...
Polarization (electrochemistry) In electrochemistry, polarization is a collective term for certain mechanical side-effects (of an electrochemical process) by which isolating barriers develop at the interface between electrode and electrolyte. These side-effects influence the reaction mechanisms, as well as the chemical kinetics of corrosion and ...
Polarography is an electrochemical voltammetric technique that employs (dropping or static) mercury drop as a working electrode. In its most simple form polarography can be used to determine concentrations of electroactive species in liquids by measuring their mass-transport limiting currents. In such an experiment the potential of the working ...
Electroanalytical methods. Electroanalytical methods are a class of techniques in analytical chemistry which study an analyte by measuring the potential (volts) and/or current (amperes) in an electrochemical cell containing the analyte. [1][2][3][4] These methods can be broken down into several categories depending on which aspects of the cell ...
In electrochemistry, cyclic voltammetry (CV) is a type of potentiodynamic measurement. In a cyclic voltammetry experiment, the working electrode potential is ramped linearly versus time. Unlike in linear sweep voltammetry, after the set potential is reached in a CV experiment, the working electrode 's potential is ramped in the opposite ...
Dielectric spectroscopy (which falls in a subcategory of the impedance spectroscopy) measures the dielectric properties of a medium as a function of frequency. [2][3][4][5] It is based on the interaction of an external field with the electric dipole moment of the sample, often expressed by permittivity. It is also an experimental method of ...
Tafel plot for an anodic process (oxidation) The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.
Chronoamperometry. Double-pulsed chronoamperometry waveform showing integrated region for charge determination. In electrochemistry, chronoamperometry is an analytical technique in which the electric potential of the working electrode is stepped and the resulting current from faradaic processes occurring at the electrode (caused by the ...
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