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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Hydrogen atoms attached to atoms other than carbon must be written explicitly. An additional feature of skeletal formulas is that by adding certain structures the stereochemistry, that is the three-dimensional structure, of the compound can be determined. Often times, the skeletal formula can indicate stereochemistry through the use of wedges ...
CH 4 + Cl 2 → CH 3 Cl + HCl CH 3 Cl + Cl 2 → CH 2 Cl 2 + HCl CH 2 Cl 2 + Cl 2 → CHCl 3 + HCl CHCl 3 + Cl 2 → CCl 4 + HCl. The output of these processes is a mixture of chloromethane, dichloromethane, chloroform, and carbon tetrachloride as well as hydrogen chloride as a byproduct. These compounds are separated by distillation.
Most compounds considered to be Lewis acids require an activation step prior to formation of the adduct with the Lewis base. Complex compounds such as Et 3 Al 2 Cl 3 and AlCl 3 are treated as trigonal planar Lewis acids but exist as aggregates and polymers that must be degraded by the Lewis base. [10] A simpler case is the formation of adducts ...
2-Chloroethanol is toxic with an LD 50 of 89 mg/kg in rats. Like most organochlorine compounds, chloroethanol releases hydrochloric acid and phosgene when burned.. In regards to dermal exposure to 2-chloroethanol, the Occupational Safety and Health Administration has set a permissible exposure limit of 5 ppm (16 mg/m 3) over an eight-hour time-weighted average, while the National Institute for ...
The skeletal formula of the antidepressant drug escitalopram, featuring skeletal representations of heteroatoms, a triple bond, phenyl groups and stereochemistry. The skeletal formula, line-angle formula, bond-line formula or shorthand formula of an organic compound is a type of molecular structural formula that serves as a shorthand representation of a molecule's bonding and some details of ...
The first crystallographic study of a compound with a quadruple bond was provided by Soviet chemists for salts of Re 2 Cl 2− 8. [4] The very short Re–Re distance was noted. This short distance (and the salt's diamagnetism) indicated Re–Re bonding. These researchers, however, misformulated the anion as a derivative of Re(II), i.e., Re 2 Cl ...
Theories of chemical structure were first developed by August Kekulé, Archibald Scott Couper, and Aleksandr Butlerov, among others, from about 1858. [4] These theories were first to state that chemical compounds are not a random cluster of atoms and functional groups, but rather had a definite order defined by the valency of the atoms composing the molecule, giving the molecules a three ...