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Excess zinc will reduce the azo group to a hydrazino compound.) Aliphatic nitro compounds ... R-NO 2 + 4 NH 4 Cl + 2 Zn → R-NH-OH + 2 ZnCl 2 + 4 NH 3 + H 2 O.
The reaction was first used by Antoine Béchamp to reduce nitronaphthalene and nitrobenzene to naphthylamine and aniline, respectively. [3] The Béchamp reduction is broadly applicable to aromatic nitro compounds. [4] [5] Aliphatic nitro compounds are however more difficult to reduce, often remaining as the hydroxylamine. Tertiary aliphatic ...
Commercial selective catalytic reduction systems are typically found on large utility boilers, industrial boilers, and municipal solid waste boilers and have been shown to lower NO x emissions by 70-95%. [1] Applications include diesel engines, such as those found on large ships, diesel locomotives, gas turbines, and automobiles.
Selective non-catalytic reduction (SNCR) is a method to lessen nitrogen oxide emissions in conventional power plants that burn biomass, waste and coal.The process involves injecting either ammonia or urea into the firebox of the boiler at a location where the flue gas is between 1,400 and 2,000 °F (760 and 1,090 °C) to react with the nitrogen oxides formed in the combustion process.
The structure of an organic nitro compound. In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (−NO 2).The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally.
The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. [1] [2] In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.
Dissimilatory nitrate reduction to ammonium is a two step process, reducing NO 3 − to NO 2 − then NO 2 − to NH 4 +, though the reaction may begin with NO 2 − directly. [1] Each step is mediated by a different enzyme, the first step of dissimilatory nitrate reduction to ammonium is usually mediated by a periplasmic nitrate reductase.
NO + NO 2 + 2 NaOH → 2 NaNO 2 + H 2 O NO + NO 2 + Na 2 CO 3 → 2 NaNO 2 + CO 2. The product is purified by recrystallization. Alkali metal nitrites are thermally stable up to and beyond their melting point (441 °C for KNO 2). Ammonium nitrite can be made from dinitrogen trioxide, N 2 O 3, which is formally the anhydride of nitrous acid: