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The ultimate strength of concrete is influenced by the water-cementitious ratio (w/cm), the design constituents, and the mixing, placement and curing methods employed.All things being equal, concrete with a lower water-cement (cementitious) ratio makes a stronger concrete than that with a higher ratio. [2]
Trisodium phosphate (TSP) is an inorganic compound with the chemical formula Na 3 P O 4. It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food additive, stain remover, and degreaser. [7]
Cement hydration and strength development mainly depend on two silicate phases: tricalcium silicate (C 3 S) (), and dicalcium silicate (C 2 S) (). [1] Upon hydration, the main reaction products are calcium silicate hydrates (C-S-H) and calcium hydroxide Ca(OH) 2, written as CH in the cement chemist notation.
A single concrete block, as used for construction. Concrete is a composite material composed of aggregate bonded together with a fluid cement that cures to a solid over time. . Concrete is the second-most-used substance in the world after water, [1] and is the most widely used building material
When water is added to cement, each of the compounds undergoes hydration and contributes to the final state of the concrete. [2] Only calcium silicates contribute to the strength. Tricalcium silicate is responsible for most of the early strength (first 7 days). [3] Dicalcium silicate, which reacts more slowly, only contributes to late strength.
In industry, the various grades of sodium silicate are characterized by their SiO 2:Na 2 O weight ratio (which can be converted to molar ratio by multiplication with 1.032). The ratio can vary between 1:2 and 3.75:1. [1] Grades with ratio below 2.85:1 are termed alkaline. Those with a higher SiO 2:Na 2 O ratio are described as neutral.
To avoid the flash setting of concrete, due to the very fast hydration of the tricalcium aluminate (C 3 A), 2–5 wt. % calcium sulfate is interground with the cement clinker to prepare the cement powder. In cement chemist notation, CaSO 4 is abbreviated as C S, and CaSO 4 ·2H 2 O as C S H 2.
When water is mixed with portland cement, the product sets in a few hours and hardens over a period of weeks. These processes can vary widely, depending upon the mix used and the conditions of curing of the product, [18] but a typical concrete sets in about 6 hours and develops a compressive strength of 8 MPa in 24 hours. The strength rises to ...
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