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A prominent feature of the pore emerged: when reconstituted into planar lipid bilayers, there is a voltage-dependent switch between an anion-selective high-conductance state with high metabolite flux and a cation-selective low-conductance state with limited passage of metabolites.
The opposing Donnan effects cause chloride ions to migrate inside the cell, increasing the intracellular chloride concentration. The Donnan effect may explain why some red blood cells do not have active sodium pumps; the effect relieves the osmotic pressure of plasma proteins, which is why sodium pumping is less important for maintaining the ...
Volume-regulated anion channels (VRACs) are crucial to the regulation of cell size by transporting chloride ions and various organic osmolytes, such as taurine or glutamate, across the plasma membrane, [1] and that is not the only function these channels have been linked to. Some research has also suggested that VRACs may be water-permeable as ...
The apexes of the anion plot are sulfate, chloride and carbonate plus hydrogen carbonate anions. The two ternary plots are then projected onto a diamond. [ 3 ] The diamond is a matrix transformation of a graph of the anions ( sulfate + chloride / total anions) and cations ( sodium + potassium /total cations).
The open conformation of the ion channel allows for the translocation of ions across the cell membrane, while the closed conformation does not. Voltage-gated ion channels are a class of transmembrane proteins that form ion channels that are activated by changes in a cell's electrical membrane potential near the channel.
Kosmotropic anions are more polarizable and hydrate more strongly than kosmotropic cations of the same charge density. [ 3 ] A scale can be established if one refers to the Hofmeister series or looks up the free energy of hydrogen bonding ( Δ G H B {\displaystyle \Delta G_{\rm {HB}}} ) of the salts, which quantifies the extent of hydrogen ...
Ions often move through the segments of the channel pore in a single file nearly as quickly as the ions move through the free solution. In many ion channels, passage through the pore is governed by a "gate", which may be opened or closed in response to chemical or electrical signals, temperature, or mechanical force.
In supramolecular chemistry, [1] host–guest chemistry describes complexes that are composed of two or more molecules or ions that are held together in unique structural relationships by forces other than those of full covalent bonds. Host–guest chemistry encompasses the idea of molecular recognition and interactions through non-covalent ...