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Nitrobenzene is an aromatic nitro compound and the simplest of the nitrobenzenes, with the chemical formula C 6 H 5 NO 2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced on a large scale from benzene as a precursor to aniline.
Nitrobenzenes are a group of nitro compounds consisting of one or more nitro groups as substituents on a benzene core. They have the formula C 6 H 6–n (NO 2) n, where n = 1–6 is the number of nitro groups.
If the benzene ring contains other substituents, it belongs in Category:Nitrobenzene derivatives Wikimedia Commons has media related to Nitrobenzenes . The main article for this category is Nitrobenzenes .
The compound was first synthesized in 1924 by Oldřich Turek. [3] It can be prepared by the reaction of 1,3,5-trichloro-2,4,6-trinitrobenzene with sodium azide. 1,3,5-trichloro-2,4,6-trinitrobenzene is obtained from the nitration of 1,3,5-trichlorobenzene with nitric acid and sulfuric acid.
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This compound can be prepared by the reduction of nitrobenzene with zinc in the presence of NH 4 Cl. [1] [2] Alternatively, it can be prepared by transfer hydrogenation of nitrobenzene using hydrazine as an H 2 source over a rhodium catalyst. [3]
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Sprengel suggested nitric acid, nitrates and chlorates as oxidisers, and nitro aromatics (e.g. nitrobenzene) as fuels. Other Sprengel explosives used at various times include charcoal with liquid oxygen (an oxyliquit), "Rackarock", and ANFO ammonium nitrate (oxidiser) mixed with a fuel oil (fuel), normally diesel, kerosene, or nitromethane.