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The main uses of fluoride, in terms of volume, are in the production of cryolite, Na 3 AlF 6. It is used in aluminium smelting. Formerly, it was mined, but now it is derived from hydrogen fluoride. Fluorite is used on a large scale to separate slag in steel-making. Mined fluorite (CaF 2) is a commodity chemical used in steel-making.
Ceramic grade fluorite (85–95% CaF 2) is used in the manufacture of opalescent glass, enamels, and cooking utensils. The highest grade, "acid grade fluorite" (97% or more CaF 2), accounts for about 95% of fluorite consumption in the US where it is used to make hydrogen fluoride and hydrofluoric acid by reacting the fluorite with sulfuric acid ...
Terlinguaite Hg 2 OCl; Tolbachite CuCl 2; Villiaumite NaF; Yttrocerite (Ca,Y,Ce)F 2; Yttrofluorite (Ca,Y)F 2; Zavaritskite (BiO)F; Many of these minerals are water-soluble and are often found in arid areas in crusts and other deposits as are various borates, nitrates, iodates, bromates and the like. Others, such as the fluorite group, are not ...
The fluorite structure refers to a common motif for compounds with the formula MX 2. [1] [2] The X ions occupy the eight tetrahedral interstitial sites whereas M ions occupy the regular sites of a face-centered cubic (FCC) structure. Many compounds, notably the common mineral fluorite (CaF 2), adopt this structure.
[1]: 53 Pliny describes the mineral as having a "great variety of colours" with "shades of purple and white with a mixture of the two". [1]: 53 Whether this mineral was banded fluorite is uncertain, but it was apparently soft enough (like fluorite) to allow one particular man of consular rank to gnaw at the edges of his cup.
Fluorite mining (the main source of fluorine) was estimated in 2003 to be a $550 million industry, extracting 4.5 million tons per year. [4] Mined fluorite is separated into two main grades, with about equal production of each. Acidspar is at least 97% CaF 2; metspar is much lower purity, 60–85%.
After hydrogen fluoride, KF is the primary source of the fluoride ion for applications in manufacturing and in chemistry. It is an alkali halide salt and occurs naturally as the rare mineral carobbiite. Solutions of KF will etch glass due to the formation of soluble fluorosilicates, although HF is more effective.
Though elemental fluorine (F 2) is very rare in everyday life, fluorine-containing compounds such as fluorite occur naturally as minerals. Naturally occurring organofluorine compounds are extremely rare. Man-made fluoride compounds are common and are used in medicines, pesticides, and materials.