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The term electromeric effect is no longer used in standard texts and is considered as obsolete. [1] The concepts implied by the terms electromeric effect and mesomeric effect are absorbed in the term resonance effect. [2] This effect can be represented using curved arrows, which symbolize the electron shift, as in the diagram below:
The mesomeric effect is negative (–M) when the substituent is an electron-withdrawing group, and the effect is positive (+M) when the substituent is an electron donating group. Below are two examples of the +M and –M effect. Additionally, the functional groups that contribute to each type of resonance are given below.
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
This electronic displacement in turn may be due to certain effects, some of which are permanent (inductive and mesomeric effects), and the others are temporary (electromeric effect). Those effects which are permanently operating in the molecule are known as polarization effects, and those effects which are brought into play by attacking reagent ...
Lenard effect (physics) Lense–Thirring effect (effects of gravitation) (tests of general relativity) Leveling effect (chemistry) Levels-of-processing effect (educational psychology) (psychology) (psychological theories) Liquid Sky (effect) (lasers) (stage lighting) Little–Parks effect (condensed matter physics) Lockin effect (physics)
Inductive Effect Electromeric Effect The polarization of a single σ covalent bond due to the electronegativity difference. Transfer of shared π-bond electron pairs to one atom under the influence of a strong external field. Permanent effect. Temporary effect. Always observed. Only observed in the presence of an electrophilic reagent.
An electric effect influences the structure, reactivity, or properties of a molecule but is neither a traditional bond nor a steric effect. [1] In organic chemistry , the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry ( stereochemistry ) of a molecule.
Some examples are: Atmospheric electricity; Biefeld–Brown effect — Thought by the person who coined the name, Thomas Townsend Brown, to be an anti-gravity effect, it is generally attributed to electrohydrodynamics (EHD) or sometimes electro-fluid-dynamics, a counterpart to the well-known magneto-hydrodynamics.