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Bulk polymerization or mass polymerization is carried out by adding a soluble radical initiator to pure monomer in liquid state. The initiator should dissolve in the monomer. The reaction is initiated by heating or exposing to radiation. As the reaction proceeds the mixture becomes more viscous.
Other monomer units, such as formaldehyde hydrates or simple aldehydes, are able to polymerize themselves at quite low temperatures (ca. −80 °C) to form trimers; [3] molecules consisting of 3 monomer units, which can cyclize to form ring cyclic structures, or undergo further reactions to form tetramers, [3] or 4 monomer-unit compounds.
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes
The first is known as self-assembly, which involves the formation of polymer by combining all elements of the MIP and allowing the molecular interactions to form the cross-linked polymer with the template molecule bound. The second method of formation of MIPs involves covalently linking the imprint molecule to the monomer.
Chloride cycle dealkalizers operate similar to sodium cycle cation water softeners. Like water softeners, dealkalizers contain ion-exchange resins that are regenerated with a concentrated salt solution - NaCl. In the case of a water softener, the cation exchange resin is exchanging sodium (the Na + ion of NaCl) for hardness minerals such as ...
In polymer chemistry, condensation polymers are any kind of polymers whose process of polymerization involves a condensation reaction (i.e. a small molecule, such as water or methanol, is produced as a byproduct). Natural proteins as well as some common plastics such as nylon and PETE are formed in this way.
The driving mechanism for micellization is the transfer of hydrocarbon chains from water into the oil-like interior. This entropic effect is called the hydrophobic effect. Compared to the increase of entropy of the surrounding water molecules, this hydrophobic interaction is relatively small. The water molecules are highly ordered around the ...
Fast and complete initiation of the monomer. This means that the rate at which an initiating agent activates the monomer for polymerization, must happen very quickly. How many monomers make up each polymer (the degree of polymerization) must be related linearly to the amount of monomer you started with. The dispersity of the polymer must be < 1 ...
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