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Fatty acid esters (FAEs) are a type of ester that result from the combination of a fatty acid with an alcohol. When the alcohol component is glycerol , the fatty acid esters produced can be monoglycerides , diglycerides , or triglycerides .
Wax esters of sperm whales contain C12 fatty acids and C14 fatty acid and alcohols. Monounsaturated C18 is the dominant fatty acid of most fish wax esters, with the exception of roe wax esters, which have sizeable amounts of polyunsaturated fatty acids such as 20:5n-3 , 22:5n-3 and 22:6n-3 .
Most fatty alcohols in nature are found as waxes, which are esters of fatty acids and fatty alcohols. [1] They are produced by bacteria, plants and animals for purposes of buoyancy, as source of metabolic water and energy, biosonar lenses (marine mammals) and for thermal insulation in the form of waxes (in plants and insects). [3]
An example of an ester formation is the substitution reaction between a carboxylic acid (R−C(=O)−OH) and an alcohol (R'OH), forming an ester (R−C(=O)−O−R'), where R and R′ are organyl groups, or H in the case of esters of formic acid. Glycerides, which are fatty acid esters of glycerol, are important esters in biology, being one of ...
An ester of a carboxylic acid.R stands for any group (typically hydrogen or organyl) and R ′ stands for any organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (R ′). [1]
Saturated fatty acids 16 and 18 carbons in length are the dominant types in the epidermis, [35] [36] while unsaturated fatty acids and saturated fatty acids of various other lengths are also present. [ 35 ] [ 36 ] The relative abundance of the different fatty acids in the epidermis is dependent on the body site the skin is covering. [ 36 ]
The hydroxide anion adds to the carbonyl group of the ester. The immediate product is called an orthoester. Saponification part I. Expulsion of the alkoxide generates a carboxylic acid: Saponification part II. The alkoxide ion is a strong base so the proton is transferred from the carboxylic acid to the alkoxide ion, creating an alcohol:
Triglycerides are formed from the esterification of 3 molecules of fatty acids with one molecule of trihydric alcohol, glycerol (glycerine or trihydroxy propane). In the process, 3 molecules of water are eliminated. The word "triglyceride" refers to the number of fatty acids esterified to one molecule of glycerol.