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Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions.
Transition state theory explains the dynamics of reactions. The theory is based on the idea that there is an equilibrium between the activated complex and reactant molecules. The theory incorporates concepts from collision theory, which states that for a reaction to occur, reacting molecules must collide with a minimum energy and correct ...
He was the first to investigate the activation energy of molecules by connecting Max Planck's new results concerning light with observations in chemistry. He is also known as the founder of collision theory together with the British scientist William Lewis. While Trautz published his work in 1916, Lewis published it in 1918.
At low energies, the result of the collision is the annihilation of the electron and positron, and the creation of energetic photons: e − + e + → γ + γ. At high energies, other particles, such as B mesons or the W and Z bosons, can be created. All processes must satisfy a number of conservation laws, including:
Also called the probability factor, the steric factor is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the pre-exponential factor and the collision frequency, and it is most often less than unity.
The activated intermediate is produced from the reactant only after a sufficient activation energy is acquired by collision with a second molecule M, which may or may not be similar to A. It then either deactivates from A* back to A by another collision, or reacts in a unimolecular step to produce the product(s) P. The two-step mechanism is then
Facebook comment on Captain Sully's plane crash theory about ground lights visibility and blame. Social media comment discussing a helicopter accident and expressing criticism towards the military.
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.