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Organic superbases are mostly charge-neutral, nitrogen containing species, where nitrogen act as a proton acceptor. These include the phosphazenes, phosphanes , amidines, and guanidines. Other organic compounds that meet the physicochemical or structural definitions of 'superbase' include proton chelators like the aromatic proton sponges and ...
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Well known phosphazene bases are BEMP (2-tert-Butylimino-2-diEthylamino-1,3-diMethylperhydro-1,3,2-diazaPhosphorine) with an acetonitrile pK a of the conjugate acid of 27.6 and the phosphorimidic triamide t-Bu-P 4 (pK BH + = 42.7) also known as Schwesinger base. [2]
In chemistry, the Verkade base (or Verkade superbase) is a powerful superbase with the formula P(MeNCH 2 CH 2) 3 N. A colorless oil, it is an aminophosphine although its inventor John Verkade called it proazaphosphatrane.
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Page information; Get shortened URL; Download QR code; ... Download as PDF; Printable version; In other projects ... Pages in category "Superbases" The following 18 ...