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The principle of minimum energy is essentially a restatement of the second law of thermodynamics.It states that for a closed system, with constant external parameters and entropy, the internal energy will decrease and approach a minimum value at equilibrium.
Zero-point energy (ZPE) is the lowest possible energy that a quantum mechanical system may have. Unlike in classical mechanics, quantum systems constantly fluctuate in their lowest energy state as described by the Heisenberg uncertainty principle. [1] Therefore, even at absolute zero, atoms and molecules retain some vibrational motion.
In atomic physics and quantum chemistry, the Aufbau principle (/ ˈ aʊ f b aʊ /, from German: Aufbauprinzip, lit. 'building-up principle'), also called the Aufbau rule, states that in the ground state of an atom or ion, electrons first fill subshells of the lowest available energy, then fill subshells of higher energy. For example, the 1s ...
The minimum total potential energy principle is a fundamental concept used in physics and engineering.It dictates that at low temperatures a structure or body shall deform or displace to a position that (locally) minimizes the total potential energy, with the lost potential energy being converted into kinetic energy (specifically heat).
Energy levels for an electron in an atom: ground state and excited states. After absorbing energy, an electron may jump from the ground state to a higher-energy excited state. The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system.
Hund's first rule states that the lowest energy atomic state is the one that maximizes the total spin quantum number for the electrons in the open subshell. The orbitals of the subshell are each occupied singly with electrons of parallel spin before double occupation occurs.
The First Law encompasses several principles: Conservation of energy, which says that energy can be neither created nor destroyed, but can only change form. A particular consequence of this is that the total energy of an isolated system does not change. The concept of internal energy and its relationship to temperature.
The minimization of the Gibbs free energy is a form of the principle of minimum energy (minimum 'free' energy or exergy), which follows from the entropy maximization principle for closed systems. Moreover, the Gibbs free energy equation, in modified form, can be used for open systems , including situations where chemical potential terms are ...