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Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
Hyperconjugation model for explaining the gauche effect in 1,2-difluoroethane. Key in the bent bond explanation of the gauche effect in difluoroethane is the increased p orbital character of both C−F bonds due to the large electronegativity of fluorine. As a result, electron density builds up above and below to the left and right of the ...
This phenomenon, a type of resonance, can stabilize the molecule or transition state. [2] It also causes an elongation of the σ-bond by adding electron density to its antibonding orbital. [1] Negative hyperconjugation is seldom observed, though it can be most commonly observed when the σ *-orbital is located on certain C–F or C–O bonds ...
Negative hyperconjugation is a theorized phenomenon in organosilicon compounds, in which hyperconjugation stabilizes or destabilizes certain accumulations of positive charge. The phenomenon explains corresponding peculiarities in the stereochemistry and rate of hydrolysis .
A primary kinetic isotope effect (PKIE) may be found when a bond to the isotopically labeled atom is being formed or broken. [3] [4]: 427 Depending on the way a KIE is probed (parallel measurement of rates vs. intermolecular competition vs. intramolecular competition), the observation of a PKIE is indicative of breaking/forming a bond to the isotope at the rate-limiting step, or subsequent ...
Brownian motion is the random motion of particles suspended in a medium (a liquid or a gas). [2] This motion pattern typically consists of random fluctuations in a particle's position inside a fluid sub-domain, followed by a relocation to another sub-domain. Each relocation is followed by more fluctuations within the new closed volume.
Depending on the frequency of flash, the element appears motionless or rotating in reverse direction. The stroboscopic effect is a visual phenomenon caused by aliasing that occurs when continuous rotational or other cyclic motion is represented by a series of short or instantaneous samples (as opposed to a continuous view) at a sampling rate ...
The Magnus effect is a phenomenon that occurs when a spinning object is moving through a fluid. A lift force acts on the spinning object and its path may be deflected in a manner not present when it is not spinning. The strength and direction of the Magnus effect is dependent on the speed and direction of the rotation of the object. [1]