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Powdered potassium sulfide anhydrous. Potassium sulfide is an inorganic compound with the formula K 2 S. The colourless solid is rarely encountered, because it reacts readily with water, a reaction that affords potassium hydrosulfide (KSH) and potassium hydroxide (KOH). Most commonly, the term potassium sulfide refers loosely to this mixture ...
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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Potassium hydrosulfide is an inorganic compound with the formula KSH. This colourless salt consists of the cation K + and the bisulfide anion [SH] −. It is the product of the half-neutralization of hydrogen sulfide with potassium hydroxide. The compound is used in the synthesis of some organosulfur compounds. [1]
The salt is prepared by the addition of elemental sulfur to potassium sulfide. An idealized equation is shown for potassium hydrosulfide: 4 KSH + S 8 → 2 K 2 S 5 + 2 H 2 S. The structure consists of zigzag chains of S 2− 5 paired with K + ions. [2]
Potassium oxide is produced from the reaction of oxygen and potassium; this reaction affords potassium peroxide, K 2 O 2. Treatment of the peroxide with potassium produces the oxide: [5] K 2 O 2 + 2 K → 2 K 2 O. Alternatively and more conveniently, K 2 O is synthesized by heating potassium nitrate with metallic potassium: 2 KNO 3 + 10 K → 6 ...
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