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Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
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It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq). The word aqueous (which comes from aqua) means pertaining to, related to, similar to, or dissolved in, water.
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
At 25 °C with pH 7 ([H +] = 1.0 × 10 −7 M), the potential is unchanged based on the Nernst equation. The thermodynamic standard cell potential can be obtained from standard-state free energy calculations to find ΔG° and then using the equation: ΔG°= −n F E° (where E° is the cell potential and F the Faraday constant, 96,485 C/mol ...
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
An element–reaction–product table is used to find coefficients while balancing an equation representing a chemical reaction. Coefficients represent moles of a substance so that the number of atoms produced is equal to the number of atoms being reacted with. [1] This is the common setup: Element: all the elements that are in the reaction ...