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K 2 Cr 2 O 7 (aq) + 2 KOH → 2 K 2 CrO 4 + H 2 O. Or, the fusion of potassium hydroxide and chromium trioxide: 2 KOH + CrO 3 → K 2 CrO 4 + H 2 O. In solution, the behavior of potassium and sodium dichromates are very similar. When treated with lead(II) nitrate, it gives an orange-yellow precipitate, lead(II) chromate.
Commercially available chromium(III) chloride hydrate is the dark green complex [CrCl 2 (H 2 O) 4]Cl. Closely related compounds are the pale green [CrCl(H 2 O) 5 ]Cl 2 and violet [Cr(H 2 O) 6 ]Cl 3 . If anhydrous violet [ 10 ] chromium(III) chloride is dissolved in water, the violet solution turns green after some time as the chloride in the ...
The Cr 2 (OAc) 4 (H 2 O) 2 molecule contains two atoms of chromium, two ligated molecules of water, and four acetate bridging ligands.The coordination environment around each chromium atom consists of four oxygen atoms (one from each acetate ligand) in a square, one water molecule (in an axial position), and the other chromium atom (opposite the water molecule), giving each chromium centre an ...
3 O 2− 10, and tetrachromates, Cr 4 O 2− 13. [2] All polyoxyanions of chromium(VI) have structures made up of tetrahedral CrO 4 units sharing corners. [3] The hydrogen chromate ion, HCrO 4 −, is a weak acid: HCrO − 4 ⇌ CrO 2− 4 + H +; pK a ≈ 5.9. It is also in equilibrium with the dichromate ion: 2 HCrO − 4 ⇌ Cr 2 O 2− 7 + H 2 O
Chrome alum. Chromium alum is produced from chromate salts or from ferrochromium alloys. Concentrated aqueous solutions of potassium dichromate can be reduced, usually with sulfur dioxide but also with alcohols or formaldehyde, in the presence of sulfuric acid at temperatures <40 °C.
Structure of [Co 2 (OH 2) 10] 4+ color code: red = O, white = H, blue = Co. In the binuclear ion [Co 2 (OH 2) 10] 4+ each bridging water molecule donates one pair of electrons to one cobalt ion and another pair to the other cobalt ion. The Co-O (bridging) bond lengths are 213 picometers, and the Co-O (terminal) bond lengths are 10 pm shorter.
In its pure form it may be called tritium oxide (T 2 O or 3 H 2 O) or super-heavy water. Pure T 2 O is a colorless liquid, [1] and it is corrosive due to self-radiolysis. Diluted, tritiated water is mainly H 2 O plus some HTO (3 HOH). It is also used as a tracer for water transport studies in life-science research.
2 CrCl 3 + H 2 → 2 CrCl 2 + 2 HCl. or by electrolysis. On the laboratory scale, LiAlH 4, zinc, and related reductants produce chromous chloride from chromium(III) precursors: 4 CrCl 3 + LiAlH 4 → 4 CrCl 2 + LiCl + AlCl 3 + 2 H 2 2 CrCl 3 + Zn → 2 CrCl 2 + ZnCl 2. CrCl 2 can also be prepared by treating a solution of chromium(II) acetate ...